2种防护涂层体系在湿热海洋环境下防护性能的劣化规律研究

目的 研究2种防护涂层体系在湿热海洋环境下自然暴露3 a的防护性能劣化规律。方法 确定试验件为钢–铝(钢)螺接连接件,试验地点为海南万宁,并按周期测得不同暴露时间下涂层A和涂层B的外观形貌、色差、光泽度、表面傅里叶红外光谱、电化学阻抗的相关数据。通过对比分析测试结果,判断2种涂层在不同暴露时间下的劣化程度,并最终得到其劣化规律。结果 涂层A自然暴露1 a老化严重,紧固件区域涂层剥落,平板区域失光率约为75%,阻抗模量降低5个数量级,色差ΔE^*为5(轻微变色),涂层有机基团老化降解严重。涂层B自然暴露2 a,老化较严重,紧固件区域涂层剥落、生锈,平板失光率约为20%,阻抗模量降低2个数量级,色差ΔE^*为11(严重变色),涂层有机基团轻微老化降解。结论 对于螺钉连接结构,连接区域不仅更容易被腐蚀,而且增加了附近平板区域的不一致性。涂层体系B的保护能力优于涂层体系A,涂层体系B的有效保护时间约为2 a,而涂层体系A则不到1 a。     

一种基于综合环境剖面的导弹弹上设备加速贮存试验方法

目的 基于导弹武器在历经地面使用载荷后,还要满足飞行载荷的特点,讨论用于评估导弹弹上设备贮存期的加速贮存试验流程与方法。方法 开展加速因子试验,获得加速因子计算公式,根据实际使用环境载荷,制定综合环境试验剖面,按照贮存期目标值开展加速贮存试验,等效地面使用环境载荷,开展飞行环境载荷考核试验,试验成功后,给出贮存期评估结论。结果 该方法在多型导弹贮存延寿工程的弹上设备贮存期评估中得到应用,应用表明,可以评估导弹弹上设备的贮存期,具有工程应用价值。结论 获得加速因子计算公式后,将导弹弹上设备的地面使用环境载荷累计影响与能够经受飞行载荷环境分步进行试验,能够体现导弹弹上设备历经的环境载荷,可以用于弹上设备的贮存期评估。     

车用高分子材料不同地区户外曝晒试验相关性研究

目的将3种高分子材料以及3种车用外饰材料分别投放在中国海南琼海和美国佛罗里达州2种典型湿热环境中进行户外曝晒试验,研究气候相似的2种地区的试验相关性。方法通过测试相同时间间隔下不同材料在2处试验场曝晒过程中的黄变程度,表征材料的老化现象。采用斯皮尔曼等级相关系数的统计方法,研究材料在2个地区相同时间节点的试验结果的相关性,并利用时间同轴的作图方法比较2个地区严酷度的差异。结果琼海与佛罗里达州2个地区在各个时间节点的相关系数接近于1,且在材料黄变方面呈现一定比例关系。结论琼海和佛罗里达州2个地区的试验结果呈现出较好的相关性,且严酷度比值约为琼海︰佛罗里达=1︰1.19。     

CN-测定中显色剂配制方法的选择与保存时间

对2种氰化物显色剂配制方法进行了对比，发现用无水乙醇配制的显色剂具有方便，经济，实用，无毒且显色剂保存期长等优势。     

家庭生活用水与室内氡浓度研究与进展

文章论述了家庭生活水的氡浓度水平、生活用水对室内氡的贡献、水的使用过程中室内氡行为以及含氡水的使用与辐射照射剂量的关系等问题。指出家庭生活水的氡浓度高时，是室内氡的一个不可忽视的来源。对氡浓度特别高的家庭用水，建议先用活性炭等进行吸附后再使用。     

Acute exposure to chemicals during ‘do-it-yourself’ activities: survey of enquiries to the Swedish Poisons Information Centre in 1996

In 1996 the Swedish Poisons Information Centre performed a follow-up study concerning poisonings related to ‘do-it-yourself’ activities. The study was supported by the National Institute of Public Health in Sweden. The objectives were to investigate and define monthly variations, route of exposure, type of products and, in particular, exposures to corrosives, age and sex groups, place of treatment, severity of symptoms, place of the accident, special risk products and risk situations. The Poisons Information Centre was contacted concerning 1609 cases, with a peak during the summer months. There was no or uncertain connection between exposure and symptoms in 117 cases. This means that 1492 cases were left to study. Inhalation and eye exposure were the predominant routes, followed by skin exposure and ingestion. Cleaning agents were the most common type of products involved. Of the 1492 cases included in the study 1033 were possible to follow up. Among these, 20–29 year olds and 30–39 year olds predominated, and there was a dominance for men. In total, 28% of those exposed were subject to medical attention, either in hospital or in outpatient clinics. According to the Poisoning Severity Score 78% had mild (grade 1) and 7% moderate (grade 2) symptoms. There were no severe intoxications and no deaths. Severity grade 2 occurred 3.6 times more often among those with exposures involving risk of corrosive damage than among others in the study population. Most accidents occurred in the home. Special risk products and risk situations were exposure to corrosive products, release of chlorine when mixing hypochlorite and acid, ‘fire-eating’, siphoning gasoline and diesel fuel, welding, and inhalation of carbon monoxide from exhaust gases. The Swedish Poisons Information Centre registered 1609 cases of poisoning accidents during ‘do-it-yourself’ activities, which means an average of four to five cases per day. Although this type of accidents is not uncommon, significant poisoning seems to be rare. Some special risk situations were identified.     

Biomonitoring of pyrethroid exposure among rural and urban populations in northern Poland

The aim of this study was to determine for the first time in Poland, levels of exposure to synthetic pyrethroids in preschool and school age children and their parents living in urban and rural areas. For this purpose concentrations of pyrethroid metabolites: 3-phenoxybenzoic acid (3-PBA), 2,2-dibromovinyl-2,2-dimethylcyclopropanecarboxylic acid (Br₂CA), cis-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane-1-carboxylic acid (cis-Cl₂CA) and trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane-1-carboxylic acid (trans-Cl₂CA) were determined in 374 urine samples using a validated GC–MS method.     

Brominated flame retardants in dust from UK cars--within-vehicle spatial variability, evidence for degradation and exposure implications

Polybrominated diphenyl ethers (PBDEs), hexabromocyclododecanes (HBCDs), and tetrabromobiphenol-A (TBBP-A) were measured in a preliminary study of dust from passenger cabins and trunks of 14 UK cars. Concentrations in cabin dust of HBCDs, TBBP-A, and BDEs 47, 85, 99, 100, 153, 154, 183, 196, 197, 202, 203, 206, 207, 208, and 209 exceeded significantly (p < 0.05) those in trunk dust. Sampling cabin dust thus appears to provide a more accurate indicator of human exposure via car dust ingestion than trunk dust. Elevated cabin concentrations are consistent with greater in-cabin use of BFRs. In five cars, while no significant differences (p > 0.05) in concentrations of HBCDs and most PBDEs were detected in dust sampled from four different seating areas; concentrations of TBBP-A and of PBDEs 154, 206, 207, 208, and 209 were significantly higher (p < 0.05) in dust sampled in the front seats. Possible photodebromination of BDE-209 was indicated by significantly higher (p < 0.05) concentrations of BDE-202 in cabin dust. In-vehicle exposure via dust ingestion to PBDEs, HBCDs and TBBP-A exceeded that via inhalation. Comparison with overall exposure via diet, dust ingestion, and inhalation shows while in-vehicle exposure is a minor contributor to overall exposure to BDE-99, ΣHBCDs, and TBBP-A, it is a significant pathway for BDE-209.     

新型全氟化合物——全氟烷基磷酸对环境影响的研究综述

全氟烷基磷酸是一种新型全氟化表面活性剂,被广泛应用于匀染剂、湿润剂和农药中的消泡添加剂等。在美国,基于对其潜在毒性的考虑,美国环境保护总署已禁止全氟烷基磷酸在粮食作物农药中使用。从全氟烷基磷酸的注册使用情况、结构与环境行为、环境介质中的浓度水平和生物暴露毒性等方面分别展开论述,旨在为中国开展该类物质的环境研究提供可借鉴依据。